should optical mineralogy fail to identify the species of sulphide/compound then you can progress to microscopes that examine, image and analyse the elemental make up of a compound using a beam of accelerated electrons, an electron microscope.
The article that you have referenced in your post relates to a completely different field of science called X-ray crystallography (or crystallography).
that uses very high energy electromagnetic radiation, X-Rays, to determine the atomic and molecular structure of crystals.
An unusual gold-silver sulphide like uytenbogaardtite can be completely visible and identifiable with the naked eye or under an optical microscope (in the case that the sulphide crystals are small and disseminated in the rock), but its full crystalline structure (like all minerals) can only be determined properly using high energy radiation like X-Rays. The pattern of transmitted X-Rays is computed back to reconstruct the arrangements (and symmetry groups) of the atoms in the crystal lattice which will help explain certain physical properties of the crystal (mineral) like the various shapes/forms it has in nature etc.
Below is an image of uytenbogaardtite plainly visible in reflected light at what seems like a low magnification. Below that is another image of the same sulphide clearly visible with the naked eye (1mm scale crystals). No need for any fancy microscopes with that sample. Probably also no need for any fancy assays either.
It's OK if you want to remain Comfortably Numb, some of us prefer solid explanations of things.